The Difference Between Primary Lithium Primary Battery and Lithium Ion Battery
Apr. 16, 2025
A lithium battery is a type of battery that uses lithium metal or lithium alloy as the negative electrode material, along with a non-aqueous electrolyte solution.
Lithium batteries are divided into two categories: non-rechargeable and rechargeable. Non-rechargeable batteries are called primary batteries, which can only convert chemical energy into electrical energy at one time, and cannot restore electrical energy back to chemical energy. Examples include lithium-manganese dioxide and lithium-thionyl chloride primary batteries.
On the other hand, rechargeable batteries, or secondary batteries (also called accumulators), can store electrical energy as chemical energy and convert it back to electrical energy when in use. This process is reversible. A common example is the lithium-ion battery found in mobile phones and many other consumer electronics.
The difference between lithium and lithium-ion batteries is that one is not rechargeable (primary cell) and the other can be recharged (secondary cell). In addition to this, Lithium batteries have a shelf life up to four times longer than lithium-ion batteries and are also much cheaper and easier to make.
1. Lithium Primary Battery
Also known as a primary lithium battery, this type of battery can be discharged either continuously or intermittently. Once the battery is depleted, it cannot be reused. Lithium primary batteries are commonly used in low-power electronic devices like cameras.
These batteries have an exceptionally low self-discharge rate, allowing them to be stored for up to 3 years. For optimal storage, keeping them in a cool environment, such as refrigeration, can further enhance their longevity. However, do not confuse lithium primary batteries with lithium-ion batteries. Lithium primary batteries cannot be recharged, and attempting to charge them is extremely dangerous!
2. Lithium-Ion Battery
Also known as a secondary lithium battery, this type of battery has a low self-discharge rate and can be stored for over six months at 20°C without significant capacity loss.
However, it’s important to manage the self-discharge phenomenon in lithium-ion batteries. If the battery voltage drops below 3.6V for an extended period, it can lead to over-discharge, damaging the internal structure and reducing the battery’s lifespan. To maintain optimal performance, lithium-ion batteries should be recharged every 3 to 6 months. The recommended storage voltage is between 3.8V and 3.9V (ideally around 3.85V), with the battery's charge depth maintained at 40% to 60%—never fully charged.
For long-term storage, keep the battery in a dry environment, ideally between 4°C and 35°C. It should be kept in moisture-proof packaging, away from heat sources, and not exposed to direct sunlight.
Comparison Dimension | Primary Lithium Battery | Lithium-Ion Battery |
Rechargeability | Non-rechargeable (single-use) | Rechargeable (designed for hundreds to thousands of cycles) |
Battery Type | Primary cell | Secondary cell |
Anode Material | Metallic lithium | Graphite or other lithium-intercalated compounds |
Cathode Material | Typically manganese dioxide, thionyl chloride, etc. | Lithium metal oxides (e.g., LiCoO₂, LiFePO₄, NMC, etc.) |
Nominal Voltage | Varies (around 1.5 V up to 3.7 V per cell) | Typically ~3.6–3.7 V per cell (up to ≈4.2 V when fully charged) |
Energy Density | Very high initial energy density by weight | Competitive energy density with the added benefit of rechargeability |
Self-Discharge/Shelf Life | Extremely low self-discharge; capable of retaining charge for many years | Higher self-discharge and gradual capacity fade over time |
Applications | Low-drain, long-life devices (e.g., cameras, watches, medical devices) | High-drain and frequently used devices (e.g., smartphones, laptops, EVs) |
Safety & Management | Simple construction; not designed for charging; attempting to recharge may be dangerous | Requires integrated protection circuits and battery management systems to prevent overcharge, deep discharge, and thermal issues |
Summary and Practical Implications
Primary lithium batteries are best when you need a battery that lasts for years without needing to be recharged (think of devices that are rarely accessed or need to work “out of the box” in critical scenarios). They are simpler, often offer excellent shelf life, and have high initial energy density but cannot be recharged.
Lithium-ion batteries are the workhorses of modern electronics. They support repeated recharging cycles, making them ideal for our daily-use devices such as phones, laptops, and electric vehicles. The trade-off comes in the form of a more complex design requiring sophisticated management circuitry and a generally higher self-discharge rate.